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We present Karl G. Jansky Very Large Array S - (2–4 GHz), C - (4–8 GHz), and X -band (8–12 GHz) continuum observations toward seven radio-loud quasars at z  > 5. This sample has previously been found to exhibit spectral peaks at observed-frame frequencies above ∼1 GHz. We also present upgraded Giant Metrewave Radio Telescope (uGMRT) band-2 (200 MHz), band-3 (400 MHz), and band-4 (650 MHz) radio continuum observations toward eight radio-loud quasars at z  > 5, selected from our previous GMRT survey, in order to sample their low-frequency synchrotron emission. Combined with archival radio continuum observations, all ten targets show evidence for spectral turnover. The turnover frequencies are ∼1–50 GHz in the rest frame, making these targets gigahertz-peaked-spectrum or high-frequency-peaker candidates. For the nine well-constrained targets with observations on both sides of the spectral turnover, we fit the entire radio spectrum with absorption models associated with synchrotron self-absorption and free-free absorption (FFA). Our results show that FFA in an external inhomogeneous medium can accurately describe the observed spectra for all nine targets, which may indicate an FFA origin for the radio spectral turnover in our sample. As for the complex spectrum of J114657.79+403708.6 at z  = 5.00 with two spectral peaks, it may be caused by multiple components (i.e., core-jet) and FFA by the high-density medium in the nuclear region. However, we cannot rule out the spectral turnover origin of variability. Based on our radio spectral modeling, we calculate the radio loudness R 2500 Å for our sample, which ranges from 12 −1 +1 to 674 −51 +61 . 

Abstract Using the Karl G. Jansky Very Large Array (VLA), we have conducted a survey for 22 GHz, 6 1,6 –5 2,3 H 2 O masers toward the Serpens South region. The masers were also observed with the Very Long Baseline Array following the VLA detections. We detect for the first time H 2 O masers in the Serpens South region that are found to be associated to three Class 0–Class I objects, including the two brightest protostars in the Serpens South cluster, known as CARMA-6 and CARMA-7. We also detect H 2 O masers associated to a source with no outflow or jet features. We suggest that this source is most probably a background asymptotic giant branch star projected in the direction of Serpens South. The spatial distribution of the emission spots suggest that the masers in the three Class 0–Class I objects emerge very close to the protostars and are likely excited in shocks driven by the interaction between a protostellar jet and the circumstellar material. Based on the comparison of the distributions of bolometric luminosity of sources hosting 22 GHz H 2 O masers and 162 young stellar objects covered by our observations, we identify a limit of L Bol ≈ 10 L ⊙ for a source to host water masers. However, the maser emission shows strong variability in both intensity and velocity spread, and therefore masers associated to lower-luminosity sources may have been missed by our observations. We also report 11 new sources with radio continuum emission at 22 GHz.